|
Ac |
acetyl |
|
acac |
acetylacetonate
 |
|
AIBN |
azoisobutyronitrile
 |
|
BINAP |
2,2'-bis(diphenylphosphino)-1,1'-binaphthalene
 |
|
Bn |
Benzyl |
|
tBu |
tert-butyl |
|
Bz |
benzoyl |
|
Cbz |
benzyloxycarbonyl
 |
|
Cp |
cyclopentadienyl |
|
DBU |
1,8-diazabicyclo[5.4.0]undec-7-ene
 |
|
DDQ |
2,3-dichloro-5,6-dicyano-benzoquinone
 |
|
de |
diastereoisomeric excess |
|
DEAD |
diethylazodicarboxylate |
|
DET |
diethyl tartrate
 |
|
(DHQD)2PHAL |
hydroquinidine-1,4-phthalazinediyl diether
 |
|
(DHQ)2PHAL |
hydroquinine-1,4-phthalazinediyl diether
 |
|
DIBALH |
diisobutylaluminium hydride |
|
DIPA |
diisopropylamine |
|
DIPEA |
diisopropyl(ethyl)amine |
|
DIPT |
diisopropyl tartrate |
|
DMAP |
4-dimethylaminopyridine |
|
DMDO |
dimethyldioxirane
 |
|
DME |
1,2-dimethoxyethane |
|
DMF |
dimethylformamide
 |
|
DMPU |
1,3-dimethyl-3,4,5,6-tetrahydo-2[1H]-pyrimidone
 |
|
DMS |
dimethylsulfide |
|
DMSO |
dimethylsulfoxide
 |
|
ee |
enantiomeric excess |
|
FGI |
functional group
interconversion |
|
HMPA |
hexamethylphosphoramide
 |
|
Ipc |
isopinocampheyl
 |
|
LDA |
lithium diisopropylamide |
|
LHMDS |
lithium
hexamethyldisilazide
 |
|
LTMP |
lithium
tetramethylpiperidide
 |
|
mCPBA |
3-chloroperbenzoic acid (meta-chloroperbenzoic
acid) |
|
MOM |
methoxymethyl |
|
Ms |
mesyl (methanesulfonyl)
 |
|
NIS |
N-iodosuccinimide
 |
|
NMO |
N-methylmorpholine-N-oxide
 |
|
PCC |
pyridinium chlorochromate |
|
PDC |
pyridinium dichromate |
|
PMB |
para-methoxybenzyl |
|
iPr |
iso-propyl |
|
RDS |
rate determining step |
|
TBDMS |
(tert-butyl)dimethylsilyl |
|
TBDPS |
(tert-butyl)diphenylsilyl |
|
TBHP |
tert-butylhydroperoxide |
|
TES |
triethylsilyl |
|
Tf |
trifluoromethanesulfonyl |
|
THF |
tetrahydrofuran |
|
THP |
tetrahydropyranyl
 |
|
TIPS |
triisopropylsilyl |
|
TMEDA |
N,N,N',N'-tetramethylethylenediamine
 |
|
TMS |
trimethylsilyl |
|
TPAP |
tetra-n-propylammonium
perruthenate |
|
Ts |
para-toluenesulfonyl |
|
T.S. |
transition state |
|
18C6 |
18-crown-6
(1,4,7,10,18,16-hexaoxacyclooctadecane)
 |
|
))) |
ultrasound |
